This paper in situ introduced a mixture of phytic acid,methanol,water,chromium nitrate nonahydrate,N,N?dimethylformamide in polyvinyl alcohol casting solution, where phytic acid and chromium nitrate nonahydrate formed a metal organic framework (MOF) with a three?dimensional structure. Glutaraldehyde was the crosslinking agent to crosslink polyvinyl alcohol into a network structure, and a series of anion exchange membranes with a porous MOF were constructed for fuel cells(MOF@PVA). During the experiment, the structure and properties of the membranes were optimized by adjusting the Cr3+ content. Characterization and performance test results show that the obtained composite membranes are flat and uniform in morphology, with a large number of pore structures available for OH- migration and retention of water molecules. Additionally, membrane conductivity, water content, and mechanical properties increase with the rising Cr3+ mass fractions. When m(Cr3+)/m(conductive film) is 0.012, the conductivity is the highest, that is 24.9 mS/cm. The membrane conductivity is only reduced by 8% after being immersed in a 3 mol/L NaOH solution at 80
for 168 hours.